{"id":1695,"date":"2021-12-18T17:51:59","date_gmt":"2021-12-18T09:51:59","guid":{"rendered":"http:\/\/www.360mdi.com\/archives\/1695"},"modified":"2021-12-18T17:51:59","modified_gmt":"2021-12-18T09:51:59","slug":"%e8%80%90%e6%b0%b4%e8%a7%a3%e6%9c%89%e6%9c%ba%e9%94%a1%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"https:\/\/www.360mdi.com\/archives\/1695","title":{"rendered":"\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242"},"content":{"rendered":"

\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242<\/strong><\/span><\/p>\n

\u4ea7\u54c1\u540d\u79f0\uff1a\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242<\/span><\/p>\n

\u522b\u540d\uff1a\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242\uff0c\u6709\u673a\u9521\u50ac\u5316\u5242\uff0c\u8010\u6c34\u89e3\u50ac\u5316\u5242<\/span><\/p>\n

\"\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242\u6709\u673a\u9521\u50ac\u5316\u5242\t\u8010\u6c34\u89e3\u50ac\u5316\u5242\"<\/p>\n

\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242 \u6709\u673a\u9521\u50ac\u5316\u5242 \u8010\u6c34\u89e3\u50ac\u5316\u5242<\/p>\n

\u4e00\u3001\u6709\u673a\u9521\u50ac\u5316\u5242\u7b80\u4ecb<\/strong><\/span><\/p>\n

\u6709\u673a\u9521\u7c7b\u50ac\u5316\u5242\u662f\u76ee\u524d\u5728\u805a\u6c28\u916f\u4e2d\u5e94\u7528\u5e7f\u6cdb\u7684\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5176\u56fd\u5185\u5916\u7684\u751f\u4ea7\u5382\u5bb6\u4e5f\u5f88\u591a\u3002\u6709\u673a\u9521\u50ac\u5316\u5242\u5728\u805a\u6c28\u916f\u9884\u805a\u5408\u4e0e\u6210\u819c\u56fa\u5316\u4e24\u65b9\u9762\u90fd\u6709\u5f88\u597d\u7684\u50ac\u5316\u6d3b\u6027\u3002\u5e02\u9762\u4e0a\u4e3b\u8981\u7528\u7684\u6709\u673a\u9521\u7c7b\u50ac\u5316\u5242\u4e3a\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521(DBTDL)\u548c\u8f9b\u9178\u4e9a\u9521\u3002\u6709\u673a\u9521\u5316\u5408\u7269\u80fd\u4e0e\u5f02\u6c30\u9178\u6839\u4ea7\u751f\u914d\u4f4d\uff0c\u4f7f\u2500NCO\u6781\u5316\uff0c\u4ece\u800c\u4f7f\u5f02\u6c30\u9178\u916f\u5206\u5b50\u4e2d\u5e26\u6b63\u7535\u8377\u7684\u78b3\u539f\u5b50\u66f4\u52a0\u6d3b\u6cfc\uff0c\u66f4\u5bb9\u6613\u53d7\u5230\u591a\u5143\u9187\u805a\u5408\u7269\u7aef\u7f9f\u57fa\u7684\u653b\u51fb\u3002\u5728\u805a\u6c28\u916f\u5408\u6210\u4e2d\uff0c\u53d4\u80fa\u7c7b\u50ac\u5316\u5242\u867d\u7136\u5bf9\u2500NCO\/\u2500OH\u53cd\u5e94\u6709\u4e00\u5b9a\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u4f46\u5bf9\u2500NCO\/H2O\u53cd\u5e94\u7684\u50ac\u5316\u4f5c\u7528\u66f4\u5f3a\u70c8\u3002\u6709\u673a\u9521\u4e5f\u80fd\u5bf9\u2500NCO\/\u2500OH\u53cd\u5e94\u663e\u73b0\u51fa\u5f3a\u70c8\u7684\u50ac\u5316\u4f5c\u7528\u3002<\/span><\/p>\n

\u6709\u673a\u9521\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u4e0e\u5206\u5b50\u7ed3\u6784\u6709\u5173\uff0c\u5176\u6d3b\u6027\u5927\u5c0f\u987a\u5e8f\u5982\u4e0b\uff1a<\/span><\/p>\n

R2SnX2>R2SnO\u3001R2SnS>RSnX3=RSnOOH=R3SnX>R4Sn\u3002<\/span><\/p>\n

\u5bf9\u4e8e\u542b\u4e0d\u540c\u53d6\u4ee3\u57faR\u3001X\u7684\u6709\u673a\u9521\u50ac\u5316\u5242\uff0c\u5176\u50ac\u5316\u6d3b\u6027\u987a\u5e8f\u6309R\u4e3a\u2500CH3>\u2500C4H9>\u2500C6H5\uff0c\u6309X\u5219\u4e3a\u2500OH>\u2500OC4H9=\u2500SC4H9=\u2500OCOCH3>Cl> F\u3002<\/span><\/p>\n

\u6709\u673a\u9521\u7c7b\u50ac\u5316\u5242\u867d\u7136\u5728\u805a\u6c28\u916f\u4e2d\u5e94\u7528\u5f88\u5e7f\u6cdb\uff0c\u4f46\u8fd8\u662f\u5b58\u5728\u4e00\u4e9b\u7f3a\u70b9\uff1a(1)\u4e9a\u9521\u6613\u88ab\u6c27\u5316\u4e3a4\u4ef7\u9521\uff0c\u5c24\u5176\u5728\u6c34\u548c\u6c27\u5b58\u5728\u7684\u6761\u4ef6\u4e0b\uff0c\u6545\u6613\u5931\u53bb\u6d3b\u6027\uff1b(2)\u8f9b\u9178\u4e9a\u9521\u4e2d\u7684\u8f9b\u9178\u6839\u6613\u5728\u6e7f\u6c14\u6216\u7a7a\u6c14\u4e2d\u8f6c\u5316\u4e3a2\u2013\u5f02\u8f9b\u9178\uff0c\u53d8\u4e3a\u6709\u673a\u6325\u53d1\u6210\u5206\u3002\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\u7684\u50ac\u5316\u6d3b\u6027\u867d\u7136\u5f88\u9ad8\uff0c\u4f46\u5b83\u4e0d\u662f\u9009\u62e9\u6027\u50ac\u5316\u5242\u3002\u5b83\u65e2\u80fd\u50ac\u5316\u5f02\u6c30\u9178\u6839\u4e0e\u7f9f\u57fa\u7684\u5e94\uff0c\u4e5f\u80fd\u50ac\u5316\u5f02\u6c30\u9178\u6839\u4e0e\u6c34\u7684\u53cd\u5e94\u4ee5\u53ca\u916f\u57fa\u7684\u6c34\u89e3\u53cd\u5e94\u3002\u4e8c\u4e01\u57fa\u9521\u7684\u6bd2\u6027\u867d\u6ca1\u6709\u4e09\u4e01\u57fa\u9521\u5f3a\uff0c\u4f46\u4ecd\u6709\u5f88\u5f3a\u7684\u73af\u5883\u5a01\u80c1\u6027\u3002\u9521\u7c7b\u50ac\u5316\u5242\u5728\u6c34\u4e2d\u7684\u7a33\u5b9a\u6027\u4e0d\u597d\uff0c\u6613\u6c34\u89e3\u800c\u5931\u53bb\u6d3b\u6027\u3002\u56e0\u6b64\uff0c\u73b0\u5728\u66f4\u591a\u7684\u7814\u7a76\u662f\u4ee5\u65b0\u578b\u7684\u50ac\u5316\u5242\u6765\u4ee3\u66ff\u9521\u7c7b\u50ac\u5316\u5242\uff0c\u6216\u8005\u5f00\u53d1\u51fa\u6bd2\u6027\u66f4\u5c0f\u3001\u5728\u6c34\u7a33\u5b9a\u6027\u66f4\u597d\u3001\u50ac\u5316\u6548\u679c\u66f4\u597d\u7684\u9521\u7c7b\u50ac\u5316\u5242\u3002\u5927\u591a\u6570\u9521\u7c7b\u50ac\u5316\u5242\u5bf9\u6c34\u90fd\u5f88\u654f\u611f\uff0c\u4f46\u662f\u542b\u786b\u7684\u9521\u50ac\u5316\u5242\u5bf9\u6c34\u7684\u5b58\u5728\u6216\u8005\u662f\u52a0\u6c34\u7684\u53cd\u5e94\u90fd\u5f88\u7a33\u5b9a\u3002\u7528\u542b\u786b\u7684\u9521\u50ac\u5316\u5242\u4e0eDBTDL\u5bf9\u50ac\u5316MDI(\u4e8c\u57fa\u7532\u70f7\u4e8c\u5f02\u6c30\u9178\u916f)\u4e0e\u591a\u5143\u9187\u7684\u53cd\u5e94\u6d3b\u6027\u8fdb\u884c\u6bd4\u8f83\uff0c\u53d1\u73b0\u542b\u786b\u9521\u7684\u50ac\u5316\u6d3b\u6027\u6bd4DBTDL\u7565\u4f4e\uff0c\u4f46\u8010\u6c34\u6027\u6bd4DBTDL\u597d\u3002<\/span><\/p>\n

 <\/p>\n

\u4e8c\u3001\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242\u4ea7\u54c1<\/strong><\/span><\/p>\n

NT CAT T-120\u4e0eT-12\u76f8\u6bd4\uff0c\u50ac\u5316\u6d3b\u6027\u8f83\u9ad8\uff0c\u4e14\u8010\u6c34\u89e3\u6027\u4e5f\u8f83\u597d\uff0c\u50a8\u5b58\u7a33\u5b9a\uff0c\u5728\u805a\u6c28\u916f\u884c\u4e1a\u4e2d\u50ac\u5316-OH\u4e0e-NCO\u7684\u53cd\u5e94\u8fdb\u884c\uff0c\u4e3b\u8981\u7528\u4e8e\u805a\u6c28\u916f\u786c\u6ce1\u55b7\u6d82\uff0c\u80f6\u6c34\u3001\u5fae\u5b54\u5f39\u6027\u4f53\u548c\u786c\u6ce1\uff1b<\/span><\/p>\n

NT CAT T-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\uff08\u591a\u5143\u9187-\u5f02\u6c30\u9178\u916f\uff09\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0cNT CAT T-125\u4e3b\u8981\u7528\u5728\u55b7\u6d82\u6ce1\u6cab\u3001\u786c\u8d28\u805a\u6c28\u916f\u3001\u9ad8\u5f39\u6027\u8f6f\u8d28\u6a21\u5851\u6ce1\u6cab\u53ca CASE \u5e94\u7528\u4e2d\u3002<\/span><\/p>\n

 <\/p>\n

\u4e09\u3001\u8010\u6c34\u89e3\u6709\u673a\u9521\u50ac\u5316\u5242\u50a8\u8fd0\uff1a<\/strong><\/span><\/p>\n

\u5e94\u5bc6\u5c01\u4fdd\u5b58\uff0c\u50a8\u5b58\u4e8e\u5e72\u71e5\u9634\u51c9\u901a\u98ce\u4ed3\u5e93\u5185<\/span><\/p>\n

\u00a0<\/strong><\/span><\/p>\n

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