{"id":3900,"date":"2024-07-12T14:41:07","date_gmt":"2024-07-12T06:41:07","guid":{"rendered":"https:\/\/www.360mdi.com\/archives\/3900"},"modified":"2024-07-12T14:41:07","modified_gmt":"2024-07-12T06:41:07","slug":"%e4%ba%8c%e7%94%b2%e5%9f%ba%e6%b0%a7%e5%8c%96%e9%94%a1%e5%9c%a8%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e4%b8%ad%e7%9a%84%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.360mdi.com\/archives\/3900","title":{"rendered":"\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u4e8c\u7532\u57fa\u6c27\u5316\u9521\uff08Dimethyltin Oxide\uff09\uff0c\u5316\u5b66\u5f0fC2H6OSn\uff0c\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\u800c\u5728\u6709\u673a\u5408\u6210\u4e2d\u626e\u6f14\u7740\u5173\u952e\u89d2\u8272\u3002\u8fd9\u79cd\u5316\u5408\u7269\u4ee5\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u8457\u79f0\uff0c\u5c24\u5176\u5728\u4fc3\u8fdb\u916f\u5316\u3001\u7f29\u919b\u5316\u4ee5\u53ca\u5176\u5b83\u6709\u673a\u8f6c\u5316\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u4e86\u663e\u8457\u7684\u6548\u679c\u3002\u4e0b\u9762\u6211\u4eec\u5c06\u8be6\u7ec6\u63a2\u8ba8\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u51e0\u79cd\u4e3b\u8981\u5e94\u7528\u3002<\/p>\n

1. \u916f\u5316\u53cd\u5e94\u7684\u50ac\u5316<\/strong><\/h3>\n

\u916f\u5316\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u53cd\u5e94\u7c7b\u578b\u4e4b\u4e00\uff0c\u5b83\u901a\u5e38\u6d89\u53ca\u9187\u548c\u7fa7\u9178\u6216\u5176\u884d\u751f\u7269\uff08\u5982\u9178\u9150\u3001\u9170\u5364\uff09\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u751f\u6210\u916f\u548c\u6c34\u3002\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u4f5c\u4e3a\u4e00\u4e2a\u6709\u6548\u7684\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u52a0\u901f\u8fd9\u4e00\u8fc7\u7a0b\uff0c\u63d0\u9ad8\u4ea7\u7387\u5e76\u964d\u4f4e\u6240\u9700\u53cd\u5e94\u6761\u4ef6\u7684\u4e25\u82db\u5ea6\u3002\u4f8b\u5982\uff0c\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0c\u9187\u548c\u9178\u9150\u5728\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u7684\u5b58\u5728\u4e0b\u53cd\u5e94\uff0c\u751f\u6210\u916f\u7c7b\u5316\u5408\u7269\uff1a<\/p>\n

\u2212+(\u2032)2=\u2192(3)2\u2212\u2212()\u2212\u2032+2<\/span>R<\/span>\u2212<\/span><\/span>O<\/span>H<\/span>+<\/span><\/span>(<\/span>R<\/span>\u2032<\/span><\/span><\/span><\/span><\/span><\/span><\/span>)<\/span>2<\/span>C<\/span>=<\/span><\/span>O<\/span>(<\/span>C<\/span>H<\/span>3<\/span>\u200b<\/span><\/span>)2<\/span>\u200b<\/span><\/span><\/span>S<\/span>n<\/span>O<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>R<\/span>\u2212<\/span><\/span>O<\/span>\u2212<\/span><\/span>C<\/span>(<\/span>O<\/span>)<\/span>\u2212<\/span><\/span>R<\/span>\u2032<\/span><\/span><\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/p>\n

2. \u7f29\u919b\u548c\u7f29\u916e\u7684\u5f62\u6210<\/strong><\/h3>\n

\u7f29\u919b\u548c\u7f29\u916e\u662f\u901a\u8fc7\u9187\u548c\u919b\u6216\u916e\u5728\u9178\u6027\u6216\u78b1\u6027\u6761\u4ef6\u4e0b\u53cd\u5e94\u5f62\u6210\u7684\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u6709\u673a\u5316\u5b66\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u6bd4\u5982\u4f5c\u4e3a\u4fdd\u62a4\u57fa\u56e2\u6216\u5728\u5408\u6210\u8def\u7ebf\u4e2d\u4f5c\u4e3a\u4e2d\u95f4\u4f53\u3002\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u80fd\u591f\u6709\u6548\u5730\u50ac\u5316\u8fd9\u7c7b\u53cd\u5e94\uff0c\u4fc3\u8fdb\u9187\u4e0e\u919b\u6216\u916e\u7684\u7f29\u5408\uff0c\u5f62\u6210\u66f4\u52a0\u7a33\u5b9a\u7684\u7f29\u919b\u6216\u7f29\u916e\u7ed3\u6784\uff1a<\/p>\n

\u2212+\u2032\u2192(3)2\u2212\u2212\u2032+2<\/span>R<\/span>\u2212<\/span><\/span>O<\/span>H<\/span>+<\/span><\/span>R<\/span>\u2032<\/span><\/span><\/span><\/span><\/span><\/span><\/span>C<\/span>H<\/span>O<\/span>(<\/span>C<\/span>H<\/span>3<\/span>\u200b<\/span><\/span>)2<\/span>\u200b<\/span><\/span><\/span>S<\/span>n<\/span>O<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>R<\/span>\u2212<\/span><\/span>O<\/span>\u2212<\/span><\/span>R<\/span>\u2032<\/span><\/span><\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/p>\n

3. \u5236\u5907\u5176\u4ed6\u6709\u673a\u9521\u5316\u5408\u7269<\/strong><\/h3>\n

\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u4e0d\u4ec5\u672c\u8eab\u662f\u4f18\u79c0\u7684\u50ac\u5316\u5242\uff0c\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u524d\u4f53\u7528\u4e8e\u5236\u5907\u5176\u4ed6\u7684\u6709\u673a\u9521\u5316\u5408\u7269\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u4ee5\u901a\u8fc7\u8fd8\u539f\u6216\u5176\u5b83\u53cd\u5e94\u8f6c\u5316\u4e3a\u4e8c\u7532\u57fa\u4e9a\u9521\uff08(CH3)2SnH\uff09\u548c\u9521\u5185\u916f\uff08Sn-lactones\uff09\uff0c\u540e\u8005\u5728\u6709\u673a\u5408\u6210\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u5e94\u7528\uff1a<\/p>\n

(3)2+2\u2192(3)2+2<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>H<\/span>+<\/span><\/span>H<\/span>O<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n

4. \u5728\u5149\u7535\u6750\u6599\u4e2d\u7684\u5e94\u7528<\/strong><\/h3>\n

\u9664\u4e86\u4f20\u7edf\u7684\u6709\u673a\u5408\u6210\u9886\u57df\uff0c\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u8fd8\u56e0\u5176\u72ec\u7279\u7684\u5149\u7535\u6027\u80fd\u800c\u88ab\u7528\u4e8e\u65b0\u578b\u6709\u673a\u5149\u4f0f\u6750\u6599\u7684\u5f00\u53d1\u3002\u5b83\u53ef\u4ee5\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\u7684\u7ec4\u6210\u90e8\u5206\uff0c\u7528\u4e8e\u63d0\u9ad8\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u826f\u597d\u7684\u7535\u8377\u4f20\u8f93\u80fd\u529b\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n

5. \u4f5c\u4e3a\u56fa\u5316\u5242\u548c\u9632\u8150\u5242\u7684\u6dfb\u52a0\u5242<\/strong><\/h3>\n

\u5728\u6d82\u6599\u548c\u67d3\u6599\u5de5\u4e1a\u4e2d\uff0c\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u4ee5\u4f5c\u4e3a\u56fa\u5316\u5242\u6216\u9632\u8150\u5242\u7684\u6dfb\u52a0\u5242\uff0c\u6539\u5584\u4ea7\u54c1\u6027\u80fd\u3002\u5b83\u6709\u52a9\u4e8e\u52a0\u901f\u6d82\u5c42\u7684\u56fa\u5316\u8fc7\u7a0b\uff0c\u540c\u65f6\u589e\u5f3a\u5176\u5bf9\u73af\u5883\u56e0\u7d20\u7684\u62b5\u6297\u529b\uff0c\u5ef6\u957f\u4ea7\u54c1\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

\u5b89\u5168\u6027\u4e0e\u6ce8\u610f\u4e8b\u9879<\/strong><\/h3>\n

\u867d\u7136\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u5177\u6709\u8bf8\u591a\u4f18\u52bf\uff0c\u4f46\u4f7f\u7528\u65f6\u4e5f\u9700\u8c28\u614e\u3002\u6709\u673a\u9521\u5316\u5408\u7269\u666e\u904d\u5177\u6709\u4e00\u5b9a\u7684\u6bd2\u6027\uff0c\u5c24\u5176\u662f\u957f\u671f\u66b4\u9732\u6216\u9ad8\u5242\u91cf\u4e0b\u53ef\u80fd\u5bf9\u4eba\u4f53\u5065\u5eb7\u9020\u6210\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u5728\u5904\u7406\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u65f6\uff0c\u5e94\u91c7\u53d6\u9002\u5f53\u7684\u5b89\u5168\u63aa\u65bd\uff0c\u5305\u62ec\u7a7f\u6234\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\u3001\u5728\u901a\u98ce\u826f\u597d\u7684\u73af\u5883\u4e2d\u64cd\u4f5c\u4ee5\u53ca\u9075\u5b88\u5316\u5b66\u54c1\u5b89\u5168\u6307\u5357\u3002<\/p>\n

\u603b\u4e4b\uff0c\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u51ed\u501f\u5176\u5353\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u548c\u591a\u529f\u80fd\u6027\uff0c\u5728\u6709\u673a\u5408\u6210\u9886\u57df\u4e2d\u5360\u636e\u4e86\u4e00\u5e2d\u4e4b\u5730\uff0c\u4ece\u4f20\u7edf\u7684\u916f\u5316\u548c\u7f29\u5408\u53cd\u5e94\u5230\u524d\u6cbf\u7684\u5149\u7535\u6750\u6599\u5f00\u53d1\uff0c\u90fd\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u5176\u4f7f\u7528\u5e94\u5f53\u59cb\u7ec8\u9075\u5faa\u4e25\u683c\u7684\u5b89\u5168\u89c4\u8303\uff0c\u786e\u4fdd\u64cd\u4f5c\u4eba\u5458\u7684\u5065\u5eb7\u4e0e\u5b89\u5168\u3002<\/p>\n

 <\/p>\n

\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n

CAS:2212-32-0 \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n

N,N-Dicyclohexylmethylamine \u2013 Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine \u2013 Shanghai Ohans Co., LTD<\/u><\/a><\/p>\n

bismuth neodecanoate\/CAS 251-964-6 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n

stannous neodecanoate catalysts \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n

polyurethane tertiary amine catalyst\/Dabco 2039 catalyst \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n

DMCHA – morpholine<\/u><\/a><\/p>\n

N-Methylmorpholine – morpholine<\/u><\/a><\/p>\n

Polycat 41 catalyst CAS10294-43-5 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n

Polycat DBU catalyst CAS6674-22-2 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e8c\u7532\u57fa\u6c27\u5316\u9521\uff08Dimethyltin Oxide\uff09\uff0c\u5316\u5b66\u5f0fC2H6OSn\uff0c\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u6027\u8d28\u800c\u5728\u6709\u673a\u5408\u6210\u4e2d\u626e\u6f14\u7740\u5173\u952e\u89d2\u8272\u3002\u8fd9\u79cd\u5316\u5408\u7269\u4ee5\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u8457\u79f0\uff0c\u5c24\u5176\u5728\u4fc3\u8fdb\u916f\u5316\u3001\u7f29\u919b\u5316\u4ee5\u53ca\u5176\u5b83\u6709\u673a\u8f6c\u5316\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u4e86\u663e\u8457\u7684\u6548\u679c\u3002\u4e0b\u9762\u6211\u4eec\u5c06\u8be6\u7ec6\u63a2\u8ba8\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u51e0\u79cd\u4e3b\u8981\u5e94\u7528\u3002 1. \u916f\u5316\u53cd\u5e94\u7684\u50ac\u5316 \u916f\u5316\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u53cd\u5e94\u7c7b\u578b\u4e4b\u4e00\uff0c\u5b83\u901a\u5e38\u6d89\u53ca\u9187\u548c\u7fa7\u9178\u6216\u5176\u884d\u751f\u7269\uff08\u5982\u9178\u9150\u3001\u9170\u5364\uff09\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u751f\u6210\u916f\u548c\u6c34\u3002\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u4f5c\u4e3a\u4e00\u4e2a\u6709\u6548\u7684\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u52a0\u901f\u8fd9\u4e00\u8fc7\u7a0b\uff0c\u63d0\u9ad8\u4ea7\u7387\u5e76\u964d\u4f4e\u6240\u9700\u53cd\u5e94\u6761\u4ef6\u7684\u4e25\u82db\u5ea6\u3002\u4f8b\u5982\uff0c\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0c\u9187\u548c\u9178\u9150\u5728\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u7684\u5b58\u5728\u4e0b\u53cd\u5e94\uff0c\u751f\u6210\u916f\u7c7b\u5316\u5408\u7269\uff1a \u2212+(\u2032)2=\u2192(3)2\u2212\u2212()\u2212\u2032+2R\u2212OH+(R\u2032)2C=O(CH3\u200b)2\u200bSnO\u200bR\u2212O\u2212C(O)\u2212R\u2032+H2\u200bO 2. \u7f29\u919b\u548c\u7f29\u916e\u7684\u5f62\u6210 \u7f29\u919b\u548c\u7f29\u916e\u662f\u901a\u8fc7\u9187\u548c\u919b\u6216\u916e\u5728\u9178\u6027\u6216\u78b1\u6027\u6761\u4ef6\u4e0b\u53cd\u5e94\u5f62\u6210\u7684\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u6709\u673a\u5316\u5b66\u4e2d\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u6bd4\u5982\u4f5c\u4e3a\u4fdd\u62a4\u57fa\u56e2\u6216\u5728\u5408\u6210\u8def\u7ebf\u4e2d\u4f5c\u4e3a\u4e2d\u95f4\u4f53\u3002\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u80fd\u591f\u6709\u6548\u5730\u50ac\u5316\u8fd9\u7c7b\u53cd\u5e94\uff0c\u4fc3\u8fdb\u9187\u4e0e\u919b\u6216\u916e\u7684\u7f29\u5408\uff0c\u5f62\u6210\u66f4\u52a0\u7a33\u5b9a\u7684\u7f29\u919b\u6216\u7f29\u916e\u7ed3\u6784\uff1a \u2212+\u2032\u2192(3)2\u2212\u2212\u2032+2R\u2212OH+R\u2032CHO(CH3\u200b)2\u200bSnO\u200bR\u2212O\u2212R\u2032+H2\u200bO 3. \u5236\u5907\u5176\u4ed6\u6709\u673a\u9521\u5316\u5408\u7269 \u4e8c\u7532\u57fa\u6c27\u5316\u9521\u4e0d\u4ec5\u672c\u8eab\u662f\u4f18\u79c0\u7684\u50ac\u5316\u5242\uff0c\u8fd8\u53ef\u4ee5\u4f5c\u4e3a\u524d\u4f53\u7528\u4e8e\u5236\u5907\u5176\u4ed6\u7684\u6709\u673a\u9521\u5316\u5408\u7269\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u4ee5\u901a\u8fc7\u8fd8\u539f\u6216\u5176\u5b83\u53cd\u5e94\u8f6c\u5316\u4e3a\u4e8c\u7532\u57fa\u4e9a\u9521\uff08(CH3)2SnH\uff09\u548c\u9521\u5185\u916f\uff08Sn-lactones\uff09\uff0c\u540e\u8005\u5728\u6709\u673a\u5408\u6210\u4e2d\u4e5f\u6709\u5e7f\u6cdb\u5e94\u7528\uff1a (3)2+2\u2192(3)2+2(CH3\u200b)2\u200bSnO+H2\u200b\u2192(CH3\u200b)2\u200bSnH+HO2\u200b […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[19],"tags":[1365],"_links":{"self":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/3900"}],"collection":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/comments?post=3900"}],"version-history":[{"count":0,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/3900\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/media?parent=3900"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/categories?post=3900"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/tags?post=3900"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}