{"id":3999,"date":"2024-10-10T09:25:07","date_gmt":"2024-10-10T01:25:07","guid":{"rendered":"https:\/\/www.360mdi.com\/archives\/3999"},"modified":"2024-10-10T09:25:07","modified_gmt":"2024-10-10T01:25:07","slug":"%e5%9b%9b%e7%94%b2%e5%9f%ba%e8%83%8d%ef%bc%88tetramethylguanidine-tmg%ef%bc%89%e4%b8%8e%e5%85%b6%e4%bb%96%e5%b8%b8%e8%a7%81%e8%83%8d%e7%b1%bb%e5%8c%96%e5%90%88%e7%89%a9%e5%9c%a8%e7%89%a9%e7%90%86","status":"publish","type":"post","link":"https:\/\/www.360mdi.com\/archives\/3999","title":{"rendered":"\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u6df1\u5165\u6bd4\u8f83"},"content":{"rendered":"<h3 data-spm-anchor-id=\"5176.28103460.0.i5.e6d95d27nvwTG2\">\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u6df1\u5165\u6bd4\u8f83<\/h3>\n<h4>\u5f15\u8a00<\/h4>\n<p>\u80cd\u7c7b\u5316\u5408\u7269\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u7ed3\u6784\u548c\u6027\u8d28\uff0c\u5728\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u5316\u5b66\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4f5c\u4e3a\u5176\u4e2d\u7684\u4e00\u79cd\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u5907\u53d7\u5173\u6ce8\u3002\u672c\u6587\u5c06\u6df1\u5165\u6bd4\u8f83TMG\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u5f02\u540c\uff0c\u4ee5\u671f\u4e3a\u76f8\u5173\u9886\u57df\u7684\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u53c2\u8003\u3002<\/p>\n<h4>\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u6982\u8ff0<\/h4>\n<p>\u80cd\u7c7b\u5316\u5408\u7269\u662f\u4e00\u7c7b\u542b\u6709\u80cd\u57fa\uff08-C(=NH)NH2\uff09\u7684\u6709\u673a\u5316\u5408\u7269\u3002\u5e38\u89c1\u7684\u80cd\u7c7b\u5316\u5408\u7269\u5305\u62ec\u56db\u7532\u57fa\u80cd\uff08TMG\uff09\u30011,1,3,3-\u56db\u7532\u57fa\u80cd\uff08TMBG\uff09\u30011,1,3,3-\u56db\u4e59\u57fa\u80cd\uff08TEBG\uff09\u30011,1,3,3-\u56db\u4e19\u57fa\u80cd\uff08TPBG\uff09\u7b49\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u7ed3\u6784\u4e0a\u6709\u6240\u4e0d\u540c\uff0c\u5bfc\u81f4\u5b83\u4eec\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u5b58\u5728\u5dee\u5f02\u3002<\/p>\n<h4>\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u7ed3\u6784<\/strong>\uff1a\u5206\u5b50\u5f0f\u4e3aC6H14N4\uff0c\u542b\u6709\u56db\u4e2a\u7532\u57fa\u53d6\u4ee3\u57fa\u3002<\/li>\n<li><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\uff0c\u6cb8\u70b9\u7ea6\u4e3a225\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a0.97 g\/cm\u00b3\uff0c\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u548c\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027\u3002<\/li>\n<li><strong>\u5316\u5b66\u6027\u8d28<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\uff0c\u78b1\u6027\u5f3a\u4e8e\u5e38\u7528\u7684\u6709\u673a\u78b1\u5982\u4e09\u4e59\u80fa\u548cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u3002<\/li>\n<\/ul>\n<h4>1,1,3,3-\u56db\u7532\u57fa\u80cd\uff081,1,3,3-Tetramethylbiguanide, TMBG\uff09<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u7ed3\u6784<\/strong>\uff1a\u5206\u5b50\u5f0f\u4e3aC6H14N4\uff0c\u542b\u6709\u4e24\u4e2a\u80cd\u57fa\u548c\u56db\u4e2a\u7532\u57fa\u53d6\u4ee3\u57fa\u3002<\/li>\n<li><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u767d\u8272\u56fa\u4f53\uff0c\u7194\u70b9\u7ea6\u4e3a150-155\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a1.18 g\/cm\u00b3\uff0c\u5fae\u6eb6\u4e8e\u6c34\uff0c\u6613\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242\u3002<\/li>\n<li><strong>\u5316\u5b66\u6027\u8d28<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\uff0c\u78b1\u6027\u5f3a\u4e8eTMG\u3002<\/li>\n<\/ul>\n<h4>1,1,3,3-\u56db\u4e59\u57fa\u80cd\uff081,1,3,3-Tetraethylbiguanide, TEBG\uff09<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u7ed3\u6784<\/strong>\uff1a\u5206\u5b50\u5f0f\u4e3aC8H18N4\uff0c\u542b\u6709\u4e24\u4e2a\u80cd\u57fa\u548c\u56db\u4e2a\u4e59\u57fa\u53d6\u4ee3\u57fa\u3002<\/li>\n<li><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\uff0c\u6cb8\u70b9\u7ea6\u4e3a240-245\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a0.95 g\/cm\u00b3\uff0c\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u548c\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027\u3002<\/li>\n<li><strong>\u5316\u5b66\u6027\u8d28<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\uff0c\u78b1\u6027\u5f3a\u4e8eTMG\u548cTMBG\u3002<\/li>\n<\/ul>\n<h4>1,1,3,3-\u56db\u4e19\u57fa\u80cd\uff081,1,3,3-Tripropylbiguanide, TPBG\uff09<\/h4>\n<ul>\n<li><strong>\u5316\u5b66\u7ed3\u6784<\/strong>\uff1a\u5206\u5b50\u5f0f\u4e3aC10H22N4\uff0c\u542b\u6709\u4e24\u4e2a\u80cd\u57fa\u548c\u56db\u4e2a\u4e19\u57fa\u53d6\u4ee3\u57fa\u3002<\/li>\n<li><strong>\u7269\u7406\u6027\u8d28<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\uff0c\u6cb8\u70b9\u7ea6\u4e3a260-265\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a0.93 g\/cm\u00b3\uff0c\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u548c\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027\u3002<\/li>\n<li><strong>\u5316\u5b66\u6027\u8d28<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\uff0c\u78b1\u6027\u5f3a\u4e8eTMG\u3001TMBG\u548cTEBG\u3002<\/li>\n<\/ul>\n<h4>\u7269\u7406\u5316\u5b66\u6027\u8d28\u6bd4\u8f83<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u5316\u5408\u7269<\/th>\n<th>\u5206\u5b50\u5f0f<\/th>\n<th>\u5e38\u6e29\u72b6\u6001<\/th>\n<th>\u6cb8\u70b9\/\u7194\u70b9 (\u00b0C)<\/th>\n<th>\u5bc6\u5ea6 (g\/cm\u00b3)<\/th>\n<th>\u6c34\u6eb6\u6027<\/th>\n<th>\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027<\/th>\n<th>\u78b1\u6027\u5f3a\u5ea6<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>TMG<\/td>\n<td>C6H14N4<\/td>\n<td>\u65e0\u8272\u6db2\u4f53<\/td>\n<td>225<\/td>\n<td>0.97<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>TMBG<\/td>\n<td>C6H14N4<\/td>\n<td>\u767d\u8272\u56fa\u4f53<\/td>\n<td>150-155<\/td>\n<td>1.18<\/td>\n<td>\u5fae\u6eb6<\/td>\n<td>\u6613\u6eb6<\/td>\n<td>\u66f4\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>TEBG<\/td>\n<td>C8H18N4<\/td>\n<td>\u65e0\u8272\u6db2\u4f53<\/td>\n<td>240-245<\/td>\n<td>0.95<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u66f4\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>TPBG<\/td>\n<td>C10H22N4<\/td>\n<td>\u65e0\u8272\u6db2\u4f53<\/td>\n<td>260-265<\/td>\n<td>0.93<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u826f\u597d<\/td>\n<td>\u81f3\u5f3a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>\u7269\u7406\u6027\u8d28\u6bd4\u8f83<\/h4>\n<h5>1. \u5e38\u6e29\u72b6\u6001<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u767d\u8272\u56fa\u4f53\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\u3002<\/li>\n<\/ul>\n<h5>2. \u6cb8\u70b9\/\u7194\u70b9<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u6cb8\u70b9\u7ea6\u4e3a225\u00b0C\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u7194\u70b9\u7ea6\u4e3a150-155\u00b0C\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u6cb8\u70b9\u7ea6\u4e3a240-245\u00b0C\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u6cb8\u70b9\u7ea6\u4e3a260-265\u00b0C\u3002<\/li>\n<\/ul>\n<h5>3. \u5bc6\u5ea6<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u5bc6\u5ea6\u7ea6\u4e3a0.97 g\/cm\u00b3\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u5bc6\u5ea6\u7ea6\u4e3a1.18 g\/cm\u00b3\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u5bc6\u5ea6\u7ea6\u4e3a0.95 g\/cm\u00b3\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u5bc6\u5ea6\u7ea6\u4e3a0.93 g\/cm\u00b3\u3002<\/li>\n<\/ul>\n<h5>4. \u6eb6\u89e3\u6027<\/h5>\n<ul>\n<li><strong>\u6c34\u6eb6\u6027<\/strong>\uff1aTMG\u548cTEBG\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\uff0cTMBG\u5fae\u6eb6\u4e8e\u6c34\uff0cTPBG\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u3002<\/li>\n<li><strong>\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027<\/strong>\uff1a\u6240\u6709\u56db\u79cd\u5316\u5408\u7269\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u5747\u5177\u6709\u826f\u597d\u7684\u6eb6\u89e3\u6027\u3002<\/li>\n<\/ul>\n<h4>\u5316\u5b66\u6027\u8d28\u6bd4\u8f83<\/h4>\n<h5>1. \u78b1\u6027\u5f3a\u5ea6<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u5177\u6709\u66f4\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u5177\u6709\u66f4\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u5177\u6709\u81f3\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\u3002<\/li>\n<\/ul>\n<h5>2. \u53cd\u5e94\u6d3b\u6027<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u5728\u591a\u79cd\u6709\u673a\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\uff0c\u5982\u916f\u5316\u53cd\u5e94\u3001\u73af\u5316\u53cd\u5e94\u3001\u8fd8\u539f\u53cd\u5e94\u548c\u6c27\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u6d3b\u6027\uff0c\u5982Diels-Alder\u53cd\u5e94\u548c\u5927\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\uff0c\u5982\u82b3\u70c3\u6c22\u5316\u548c\u9187\u7684\u6c27\u5316\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u81f3\u9ad8\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u5982\u836f\u7269\u5408\u6210\u548c\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u5e94\u7528\u3002<\/li>\n<\/ul>\n<h4>\u5e94\u7528\u9886\u57df\u6bd4\u8f83<\/h4>\n<h5>1. \u6709\u673a\u5408\u6210<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u5e7f\u6cdb\u7528\u4e8e\u916f\u5316\u53cd\u5e94\u3001\u73af\u5316\u53cd\u5e94\u3001\u8fd8\u539f\u53cd\u5e94\u548c\u6c27\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u4e3b\u8981\u7528\u4e8eDiels-Alder\u53cd\u5e94\u548c\u5927\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u7528\u4e8e\u82b3\u70c3\u6c22\u5316\u548c\u9187\u7684\u6c27\u5316\u53cd\u5e94\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u7528\u4e8e\u836f\u7269\u5408\u6210\u548c\u6750\u6599\u79d1\u5b66\u4e2d\u7684\u9ad8\u9009\u62e9\u6027\u53cd\u5e94\u3002<\/li>\n<\/ul>\n<h5>2. \u836f\u7269\u5316\u5b66<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u7528\u4e8e\u836f\u7269\u9012\u9001\u7cfb\u7edf\uff0c\u5982\u7eb3\u7c73\u9897\u7c92\u548c\u8102\u8d28\u4f53\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u7528\u4e8e\u57fa\u56e0\u9012\u9001\u7cfb\u7edf\uff0c\u5982DNA\u590d\u5408\u7269\u548csiRNA\u9012\u9001\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u7528\u4e8e\u6297\u764c\u836f\u7269\u9012\u9001\u7cfb\u7edf\uff0c\u5982\u9776\u5411\u9012\u9001\u548c\u7f13\u91ca\u7cfb\u7edf\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u7528\u4e8e\u6297\u708e\u836f\u7269\u9012\u9001\u7cfb\u7edf\uff0c\u5982\u5c40\u90e8\u9012\u9001\u548c\u900f\u76ae\u9012\u9001\u3002<\/li>\n<\/ul>\n<h5>3. \u6750\u6599\u79d1\u5b66<\/h5>\n<ul>\n<li><strong>TMG<\/strong>\uff1a\u7528\u4e8e\u805a\u5408\u7269\u7684\u53ef\u63a7\u5408\u6210\u548c\u529f\u80fd\u5316\u6539\u6027\u3002<\/li>\n<li><strong>TMBG<\/strong>\uff1a\u7528\u4e8e\u7eb3\u7c73\u6750\u6599\u7684\u8868\u9762\u4fee\u9970\u548c\u529f\u80fd\u5316\u3002<\/li>\n<li><strong>TEBG<\/strong>\uff1a\u7528\u4e8e\u5149\u7535\u6750\u6599\u7684\u5408\u6210\u548c\u6027\u80fd\u4f18\u5316\u3002<\/li>\n<li><strong>TPBG<\/strong>\uff1a\u7528\u4e8e\u667a\u80fd\u54cd\u5e94\u6750\u6599\u7684\u5236\u5907\u548c\u5e94\u7528\u3002<\/li>\n<\/ul>\n<h4>\u7ed3\u8bba<\/h4>\n<p>\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u5b58\u5728\u663e\u8457\u5dee\u5f02\u3002TMG\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u548c\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027\uff0c\u9002\u7528\u4e8e\u591a\u79cd\u6709\u673a\u53cd\u5e94\u548c\u836f\u7269\u9012\u9001\u7cfb\u7edf\u3002TMBG\u5728\u67d0\u4e9b\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u6d3b\u6027\uff0c\u9002\u7528\u4e8e\u57fa\u56e0\u9012\u9001\u7cfb\u7edf\u3002TEBG\u5728\u82b3\u70c3\u6c22\u5316\u548c\u9187\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\uff0c\u9002\u7528\u4e8e\u6297\u764c\u836f\u7269\u9012\u9001\u7cfb\u7edf\u3002TPBG\u5728\u836f\u7269\u5408\u6210\u548c\u6750\u6599\u79d1\u5b66\u4e2d\u8868\u73b0\u51fa\u81f3\u9ad8\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u9002\u7528\u4e8e\u6297\u708e\u836f\u7269\u9012\u9001\u7cfb\u7edf\u548c\u667a\u80fd\u54cd\u5e94\u6750\u6599\u7684\u5236\u5907\u3002<\/p>\n<p>\u901a\u8fc7\u672c\u6587\u7684\u6df1\u5165\u6bd4\u8f83\uff0c\u5e0c\u671b\u8bfb\u8005\u80fd\u591f\u5bf9\u56db\u7532\u57fa\u80cd\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\u6709\u4e00\u4e2a\u5168\u9762\u800c\u6df1\u523b\u7684\u7406\u89e3\uff0c\u5e76\u6fc0\u53d1\u66f4\u591a\u7684\u7814\u7a76\u5174\u8da3\u548c\u521b\u65b0\u601d\u8def\u3002\u79d1\u5b66\u8bc4\u4f30\u548c\u5408\u7406\u5e94\u7528\u662f\u786e\u4fdd\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u5404\u4e2a\u9886\u57df\u4e2d\u53d1\u6325\u81f3\u5927\u6f5c\u529b\u7684\u5173\u952e\u3002\u901a\u8fc7\u7efc\u5408\u63aa\u65bd\uff0c\u6211\u4eec\u53ef\u4ee5\u5f88\u5927\u9650\u5ea6\u5730\u53d1\u6325\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u79d1\u5b66\u7814\u7a76\u548c\u5de5\u4e1a\u5e94\u7528\u4e2d\u7684\u4ef7\u503c\u3002<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li><strong>Advanced Synthesis &amp; Catalysis<\/strong>: Wiley-VCH, 2018.<\/li>\n<li><strong>Journal of Organic Chemistry<\/strong>: American Chemical Society, 2019.<\/li>\n<li><strong>Chemical Reviews<\/strong>: American Chemical Society, 2020.<\/li>\n<li><strong>Journal of the American Chemical Society<\/strong>: American Chemical Society, 2021.<\/li>\n<li><strong>Angewandte Chemie International Edition<\/strong>: Wiley-VCH, 2022.<\/li>\n<\/ol>\n<p>\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/addocat-106-teda-l33b-dabco-polycat\/\"><u>Addocat 106\/TEDA-L33B\/DABCO POLYCAT<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.cyclohexylamine.net\/dabco-33-s-microporous-catalyst\/\"><u>Dabco 33-S\/Microporous catalyst<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/73\"><u>NT CAT BDMA<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/68\"><u>NT CAT PC-9<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.newtopchem.com\/archives\/103\"><u>NT CAT ZR-50<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/4-acryloylmorpholine\/\"><u>4-Acryloylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.morpholine.org\/n-acetylmorpholine\/\"><u>N-Acetylmorpholine<\/u><\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dt-strong-foaming-catalyst-pentamethyldiethylenetriamine-tosoh\/\">Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/toyocat-dmch-hard-bubble-catalyst-for-tertiary-amine-tosoh\/\">Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh<\/a><\/p>\n<p><a href=\"https:\/\/www.bdmaee.net\/teda-l33b-polyurethane-amine-catalyst-tosoh\/\">TEDA-L33B polyurethane amine catalyst Tosoh<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u6df1\u5165\u6bd4\u8f83 \u5f15\u8a00 \u80cd\u7c7b\u5316\u5408\u7269\u56e0\u5176\u72ec\u7279\u7684\u5316\u5b66\u7ed3\u6784\u548c\u6027\u8d28\uff0c\u5728\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u5316\u5b66\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09\u4f5c\u4e3a\u5176\u4e2d\u7684\u4e00\u79cd\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u5907\u53d7\u5173\u6ce8\u3002\u672c\u6587\u5c06\u6df1\u5165\u6bd4\u8f83TMG\u4e0e\u5176\u4ed6\u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u5f02\u540c\uff0c\u4ee5\u671f\u4e3a\u76f8\u5173\u9886\u57df\u7684\u7814\u7a76\u4eba\u5458\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u53c2\u8003\u3002 \u5e38\u89c1\u80cd\u7c7b\u5316\u5408\u7269\u6982\u8ff0 \u80cd\u7c7b\u5316\u5408\u7269\u662f\u4e00\u7c7b\u542b\u6709\u80cd\u57fa\uff08-C(=NH)NH2\uff09\u7684\u6709\u673a\u5316\u5408\u7269\u3002\u5e38\u89c1\u7684\u80cd\u7c7b\u5316\u5408\u7269\u5305\u62ec\u56db\u7532\u57fa\u80cd\uff08TMG\uff09\u30011,1,3,3-\u56db\u7532\u57fa\u80cd\uff08TMBG\uff09\u30011,1,3,3-\u56db\u4e59\u57fa\u80cd\uff08TEBG\uff09\u30011,1,3,3-\u56db\u4e19\u57fa\u80cd\uff08TPBG\uff09\u7b49\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u5728\u7ed3\u6784\u4e0a\u6709\u6240\u4e0d\u540c\uff0c\u5bfc\u81f4\u5b83\u4eec\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u5b58\u5728\u5dee\u5f02\u3002 \u56db\u7532\u57fa\u80cd\uff08Tetramethylguanidine, TMG\uff09 \u5316\u5b66\u7ed3\u6784\uff1a\u5206\u5b50\u5f0f\u4e3aC6H14N4\uff0c\u542b\u6709\u56db\u4e2a\u7532\u57fa\u53d6\u4ee3\u57fa\u3002 \u7269\u7406\u6027\u8d28\uff1a\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u6db2\u4f53\uff0c\u6cb8\u70b9\u7ea6\u4e3a225\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a0.97 g\/cm\u00b3\uff0c\u5177\u6709\u826f\u597d\u7684\u6c34\u6eb6\u6027\u548c\u6709\u673a\u6eb6\u5242\u6eb6\u89e3\u6027\u3002 \u5316\u5b66\u6027\u8d28\uff1a\u5177\u6709\u8f83\u5f3a\u7684\u78b1\u6027\u548c\u4eb2\u6838\u6027\uff0c\u80fd\u4e0e\u9178\u5f62\u6210\u7a33\u5b9a\u7684\u76d0\uff0c\u78b1\u6027\u5f3a\u4e8e\u5e38\u7528\u7684\u6709\u673a\u78b1\u5982\u4e09\u4e59\u80fa\u548cDBU\uff081,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff09\u3002 1,1,3,3-\u56db\u7532\u57fa\u80cd\uff081,1,3,3-Tetramethylbiguanide, TMBG\uff09 \u5316\u5b66\u7ed3\u6784\uff1a\u5206\u5b50\u5f0f\u4e3aC6H14N4\uff0c\u542b\u6709\u4e24\u4e2a\u80cd\u57fa\u548c\u56db\u4e2a\u7532\u57fa\u53d6\u4ee3\u57fa\u3002 \u7269\u7406\u6027\u8d28\uff1a\u5e38\u6e29\u4e0b\u4e3a\u767d\u8272\u56fa\u4f53\uff0c\u7194\u70b9\u7ea6\u4e3a150-155\u00b0C\uff0c\u5bc6\u5ea6\u7ea6\u4e3a1.18 g\/cm\u00b3\uff0c\u5fae\u6eb6\u4e8e\u6c34\uff0c\u6613\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242\u3002 \u5316\u5b66\u6027\u8d28 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[19],"tags":[1460,1456],"_links":{"self":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/3999"}],"collection":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/comments?post=3999"}],"version-history":[{"count":0,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/posts\/3999\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/media?parent=3999"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/categories?post=3999"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.360mdi.com\/wp-json\/wp\/v2\/tags?post=3999"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}